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2 3 5 6-Tetrafluorobenzyl alcohol, MF: C₇H₄F₄O MW: 180.10, appears as white crystalline solids. Its molecular structure features four hydrogen atoms on the benzene ring replaced by fluorine atoms (at positions 2,3,5,6), with a hydroxyl group (-CH₂OH) attached at the benzyl position (1-position). (-CH₂OH). As a fluorinated aromatic alcohol derivative bearing a benzyl hydroxyl group, tetrafluorobenzyl alcohol exhibits typical alcohol properties, undergoing esterification and substitution reactions. The fluorine atoms on the benzene ring enhance the reactivity of the benzylic hydroxyl group, making it more readily participate in nucleophilic substitution reactions.
| Item | Specification |
| Melting point | 32–38 °C |
| Boiling point | 220–225 °C |
| Density | 1.499 g/cm³ |
| Vapor pressure | 0.7 ± 0.4 mmHg at 25 °C |
| Refractive index | 1.457 |
| Flash point | 61.6 ± 25.9 °C |
| Acidity constant (pKa) | 12.94±0.10 (Predicted) |
| Solubility |
Insoluble in water; soluble in organic solvents such as benzene, diethyl ether, and dichloromethane. |
Key intermediate for synthesizing pyrethroid insecticides, providing rapid knockdown and lethal effects against household pests like mosquitoes and flies
Essential raw material for synthesizing fluorinated pyrethroids including flutopyrim, metofluthrin, and fluthrin
Serves as a fluorinated pharmaceutical intermediate for synthesizing novel antibacterial and antiviral drugs, as well as optically active pharmaceuticals
Used in synthesizing high-performance fluorinated polymers to enhance material heat resistance, chemical corrosion resistance, and mechanical properties; holds potential applications in optical functional materials
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