
P-Anisaldehyde (MF: C₈H₈O₂, MW: 136.15) is an important aromatic aldehyde compound characterized by the simultaneous attachment of a methoxy group (-OCH₃) and an aldehyde group (-CHO). It combines the chemical reactivity of the aldehyde group with the electron-withdrawing effect of the methoxy group. Naturally occurring in plants such as fennel, it is industrially synthesized primarily through the oxidation of p-methoxytoluene or the methylation of p-hydroxybenzaldehyde. It serves as a vital organic synthesis intermediate and a commonly used fragrance ingredient.
| Item | Specification |
| Melting point | 2°C |
| Boiling point | 248°C (lit.) |
| Density | 1.123 g/cm³ (20°C) |
| Vapor density | 4.7 (vs air) |
| Vapour pressure | <1 hPa (20°C) |
| Refractive index | n₂₀/D 1.573 (lit.) |
| Flash Point | 228°F |
| Odor | Possesses a distinctive aroma reminiscent of hawthorn and fennel |
| Solubility | Sparingly soluble in water; readily soluble in organic solvents such as ethanol, diethyl ether, and acetone. |
Flavor and Fragrance Industry:
– Core ingredient for hawthorn floral fragrances; also used in lilac, orchid, sunflower floral notes and non-floral fragrances like cut grass and aldehyde.
– Used in flavor formulations for vanilla, caramel, chocolate, mint, etc.
– Added to perfumes, soaps, shampoos, and other personal care products.
Pharmaceutical intermediates: Used in synthesizing antibiotics, antihistamines, and other pharmaceuticals.
Industrial and Materials Applications:
– Serves as a DE additive in cyanide-free zinc plating to enhance anode polarization and achieve bright coatings.
– Functions as a dye intermediate for synthesizing reactive dyes and direct dyes.
– Acts as a photosensitizer in dye-sensitized solar cells, offering high photoelectric conversion efficiency.
Agriculture and Environmental Protection:
– Preparation of insecticides (e.g., permethrin), fungicides (e.g., methyl p-methoxybenzaldehyde), and herbicides.
– Development of natural preservatives leveraging its antimicrobial activity to extend food shelf life.
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