
Trifluoromethanesulfonic acid (TFMSA, HOTf) is a colorless, transparent, fuming liquid; when impure, it appears yellow or yellowish-brown. It belongs to the class of perfluoroalkyl sulfonic acids and is a superacid. It is highly corrosive, hygroscopic, and strongly oxidizing, and is violently exothermically miscible with water and most polar organic solvents. It is chemically stable and exhibits excellent thermal stability, serving as a core raw material for highly efficient catalysts in organic synthesis, as well as for pharmaceutical and pesticide intermediates and electronic chemicals.
| Item | Specification |
| Melting Point | -40 °C |
| Boiling Point | 162 °C (760 mmHg) |
| Density | 1.696 g/mL (25 °C) |
| Flash Point | N/A |
| Vapor Pressure | 8 mmHg(25°C) |
| Refractive Index | n 20/D 1.327(lit.) |
| Solubility | Miscible with water, DMF, acetonitrile, and polar organics. |
| Stability | Stable; incompatible with strong bases, metals, and glass. |
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