


Ethyl acetate, also known as ethyl ethanoate, is a compound formed by replacing the hydroxyl group in acetic acid with an ethoxy group. mf:C₄H₈O₂, mw:88.11. At room temperature, it exists as a colorless, transparent liquid with a strong fruity aroma (resembling the scent of pears or bananas), serving as a key component in many natural fruit fragrances. It exhibits excellent solubility and fast drying properties, making it a versatile and critically important organic chemical feedstock and superior industrial solvent.
| Item | Specification |
| Melting point | −84°C (lit.) |
| Boiling point | 76.5–77.5°C (lit.) |
| Density | 0.902 g/mL at 25°C (lit. |
| Vapor Density | 3 (20°C, vs air) |
| Vapor Pressure | 73 mmHg (20°C) |
| Refractive Index | n20/D 1.3720 (lit.) |
| Flash Point | -3.3 ± 0.0 °C |
| Acid dissociation constant (pKa) | 16–18 (at 25°C) |
| Viscosity | 0.45 mPa·s (at 20°C) |
| APHA | ≤10 |
| Specific Gravity | 0.902 (20/20°C) |
| Relative Polarity | 0.228 |
| Odor | Sweet, fruity aroma |
| Solubility | Infinitely miscible with most organic solvents (e.g., ethanol, diethyl ether); slightly soluble in water. |
Ethyl acetate as an organic solvent:
– Ethyl ethanoate serves as a core solvent in solvent-based coatings, wood finishes, automotive paints, and printing inks; also functions as a film-forming aid in water-based coatings.
– Used in preparing solvent-based adhesives, particularly suitable for bonding plastics (PVC, ABS), rubber, leather, and similar materials.
– Ethyl ethanoate serves as an extraction agent and recrystallization solvent in pharmaceuticals, used to extract active ingredients from natural medicines, purify synthetic drugs, and as a solvent in drug formulations.
– Cleans oil and residual impurities from electronic component surfaces, leaving no residue upon evaporation; also used as a solvent for photoresists and electronic pastes.
Ethyl acetate serves as a chemical feedstock for synthesizing higher esters and ethyl acetoacetate.
Ethyl acetate in the food and flavor industry:
– Functions as a solvent and carrier for food flavorings, used in formulating fruit-based flavor profiles to enhance taste.
– Employed to extract essential oils from plants for use in perfumes, cosmetics, and food flavorings.
Other Special Applications:
– As a reaction solvent in organic synthesis, a developing agent for thin-layer chromatography (TLC), and an extraction agent.
– For cleaning oil stains and paint residues, or as a component in paint strippers for removing paint from metal and plastic surfaces.
– Used in small quantities in cigarette filters to improve the taste and aroma of smoke.
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